Humans are much more energy efficient than cars, so it was less than 3/4 of a gallon (100 kcal/mile * 200 miles = 20,000 calories = 0.7 gallons of gas or about 6 pounds of body fat). He's probably much more efficient than 100 kcal/mile though.
That said, Aleksandr is smaller than an average 40 year-old man, but actually pretty large for a distance runner, 20 kg heavier than the current world record holder in the marathon.
According to Table 1, a meat eating biker emits more CO2, than a double-occupancy Prius.
I suspect an EV would completely tip the table in favor of driving.
A car as light as a human would get something like 1,000mpg (probably a fuel cell with an electric motor).