It is indeed not proportional, but not in the way you are thinking. Drag (and ~fuel consumption) scales with velocity squared, so a plane flying twice at fast (and neglecting any time at the airport, which would make the argument even worse) would use four times as much fuel. I.e., even if twice the amount of passengers would be served, it would be done for four times the fuel consumption and four times the carbon emissions (or twice the fuel consumption per trip).