The way to find out what different groups will think about your product is to survey representative samples - not to hope that the person of background X on your team could speak for all X.
You can use focus groups for issues you don't know about - absolutely. That's one of the main benefits. Get a group to use the Go store. Ask about what they thought. Ask the people who used it a lot and those who used it a little - why did you use it so much/little. You find that some people are made uncomfortable because it feels like stealing. There - if you didn't realize that was an issue before, now you do.