In the short story series “the egg” by Andy Weir there is a similar breakthrough that leads to a zombie apocalypse:)
Even more boring of a nitpick: if the molecule provided oxygen without binding to the resulting CO2, then loss of blood flow would result in rapid carbolic acid buildup and ischemic injury from pH imbalance. You'd die from metabolic acidosis before you would die from lack of oxygen. The "respirocyte" artificial blood cell concept from 1998 had two internal tanks for that purpose, one metering out O2 and one collecting CO2: https://www.tandfonline.com/doi/pdf/10.3109/1073119980911768...
As well, could you simply not notice a malfunction and keep going until you ran out of stored oxygen?