The higher end of LED is slowly getting there. The measurement one should be looking for there is CRI ("Color Rendering Index"). The sun has a CRI of 100. Any lightsource above 90 to 95 CRI is (to my experience) indistinguishable from daylight. The best stuff there currently is are (of course) the Skypanels by ARRI for laughable 6800 USD per panel (film equipment is expensive as usual).
Blasting a 2.5 kW HMI lamp ("Hydrargyrum medium-arc iodide lamp") trough a window from the outside is a good emulation of daylight. So good in fact that the poor souls shooting films inside will have their bodies in confusion as they exit the room and realize in horror that it is dark outside.
The electrical bill of anything emulating the sun is no joke tho.