Satellite surveillance is going through a capability explosion at the moment, I wouldn't be surprised if it could spot venting in the present or near future.
1. Methane is 1900 ppb in the atmosphere[1], refrigerants overall are ~12.5 ppb -- so a lot less out there to detect. 2. I think methane leaks tend to be from single, continuing, large point sources -- coal mines, oil wells -- whereas refrigerants are usually from these distributed small point sources which happen once. So by the time you detect it it's too late to intervene.
[1] https://www.noaa.gov/news-release/increase-in-atmospheric-me...