At the low cost of a nitrogen blanket for fire safety, something like n-pentane should be suitable for immersion nucleate boiling cooling with the added benefit of not needing a heart exchanger been the immersion pool and a possible outside air hat rejection condenser.
The solvent effects are relatively well understood for these medium-light alliaphatic hydrocarbons, done care ensure that aren't particularly toxic, and a nitrogen blanket for the rooms takes care of the inherent flammability issue associated with what's basically boiling gasoline on the CPU.