https://en.wikipedia.org/wiki/Nash_equilibrium
However, if the opponent is playing sub-optimally you can win _more_ by deviating from Nash equilibrium to take advantage of their specific strategic shortcomings. The risk in doing so is if you are wrong estimating their shortcomings.. you are no longer guaranteed a tie in the worst case scenario.
You can see this play out with a small toy game and a card calculator. Suppose a two player game of Texas Holdem where each player has 8x big blinds. The first player must choose to either go all in or fold. The second player must choose to either call the all in or fold. Players must pick a range of hands to perform either action prior to looking at their cards.
https://openpokertools.com/range_equity.html
Suppose a silly strategy by the second player of folding any hand except pocket aces. You'd be wise as the first player to go all in with any hand and pick up a free big blind with 99.5% certainty. However going all in with every hand is also an easy strategy to take advantage of...
(You can actually go back and forth maximally exploiting the other player's strategy and you will eventually reach Nash equilibrium)
The short of it though is there exists a perfect range of cards the bot can play where it neither folds enough for you to bluff to gain an edge, nor does it call enough that you can wait for better cards while bleeding chips to gain an edge.
I say this despite also claiming the top DL bot does this anyway and does very well.
During the competition, Libratus used 4 million core hours on the Bridges supercomputer for analyzing it's prior gameplay and changing strategy.
> During the tournament, Libratus was competing against the players during the days. Overnight it was perfecting its strategy on its own by analysing the prior gameplay and results of the day, particularly its losses. Therefore, it was able to continuously straighten out the imperfections that the human team had discovered in their extensive analysis, resulting in a permanent arms race between the humans and Libratus.