SV COL is high, but I don't think it is high enough to explain SV pay.
Looking at a few non-SV cities such as Seattle, Chicago, Nashville, Orlando, Sacramento, Austin, and Fresno it costs $14-18k/year more to rent a 1 bedroom apartment in the Bay Area than to rent in those other places.
The average monthly spending on food in SF is about $150/month more than the US average. That's under $2K/year.
California does have a high income tax. For someone moving from somewhere else to California you might have to pay them maybe 10% more to compensate for that.
Putting it all together, a job that pays around $100k/year in non-SV non-NY decent sized cities should need to pay if we are generous maybe around $140k/year due to higher COL in the Bay Area.
That Bay Area tech pay is way more than that suggests that something other than SV COL is the main factor.