The benefit of DNA is it's conclusive: if we find DNA, then life (or an exceptionally bizarre natural process) must be their, and if we grab a sequence then it's high probability we'll be able to figure out what type of life it is due to some Earth-local proteins being basically limited in improvement by physics itself, and heavily conserved - i.e. even totally alien life would be expected to manufacture a close analogue.
Not to mention that if we turn up something totally weird, we can still synthesize it up in a lab to study.