The real problem isn't reliability but shitty dealer networks. Alfa have a knack for finding dealership networks that think it's great fun to have them in the showroom to pull people in, but aren't terribly interested in selling them or doing a good job servicing them.
My tip is to never use the dealership for servicing your vehicles (of any brand). Find a garage that has competent people, and who have respect for the work, and then pick whatever cars they are competent to work on. You don't want to spend a lot of money on a car only to have a bunch of underpaid teenagers who can only follow a manual work on your car.
I've just read the other day that BMW is recalling 1M+ vehicles on the US market because of engine fire issues. What?
Last weekend we went on a trip and what do you know, smoke coming out of the hood of a burning BMW X3 on the other side of the road, fire brigade etc. When we returned we saw it reduced to a pile of burned down chasis.
A woman from a neighbouring office bought a brand new BMW X6 (the butt ugly ones). She had to take it back to the dealership because the engine would overheat.
Another complaint I've heard of Alfas is ergonomics sacrificed for looks, which is kind of a deal breaker for me.
The ergonomics: guilty as charged. Alfas are built for people who have the anatomy of an orangutan. I am not kidding. You need short legs and freakishly long arms to be comfortable.
But I don't mind :)