To get a feel for assembly, then yes, any 8-bit CPU would be a good choice. The 8080, Z80, 6502 or 6809. There are plenty of emulated machines today, tons of material are available online, and even cross assemblers that run on modern machines to make development easier. The base concepts will carry over.
The x86 instruction set is daunting and it can appear quite arbitrary unless one knows the near 50 years of historical baggage it carries along with it. But I think if you have some experience with an 8-bit CPU, plus just kind of accept the weirdness of it, it's not that bad (especially the 64-bit stuff, which in a way, is simpler, even if half the registers are named, and half are numbered).