Bonus: they're usually white, which means you stand half a chance of being able to see the stuff in your pack. White is pretty rare except for Dyneema packs (Dyneema apparently doesn't dye).
Edited to add:
The other major failure mode for coated and laminated fabrics is when they tape the coated or laminated side. The seam tape flexes differently from the substrate fabric, which pulls at the coating or laminate. I've had coated and Goretex rain jackets fail in this way, as well as coated stuff sacks. Silnylon fares a little better because the silicone is impregnated into the nylon rather than coated on. Silnylon isn't breathable, so it isn't a mainstream material for rain gear though.
Source: GA->ME 2010 and another thousand or so miles of hiking.