Yes, but your ability to negotiate is directly tied to your value to the company. You can't negotiate without any leverage.
But the actual cost of labor (your compensation) is dictated by market forces just like any other commodity. Why would anyone hire you at $100k/year if they have someone else, just as good as you, that they can hire at $50k/year?
Your ability to negotiate is tied to your leverage, which more often than not is competing offers (including your current job). That has absolutely nothing to do with value, other than the upper bound I mentioned above.