It's the yeast strains. Some can survive higher alcohol concentrations than others.
For instance this[1] one can achieve up to 25% under right conditions.
[1] https://www.whitelabs.com/yeast-single?id=146&type=YEAST&sty...
No yeast can digest starches afaik. It's why you need a mashing phase to turn starches into simpler sugars when brewing beer.