I'd have thought it's pretty straightforwardly a case that effectiveness is capped at the percentage that comes through the material; so as long as some is, a better material will do a bit better. For sake of argument if you're getting 80% effectiveness from a perfect fit, that's 40% if 50% air comes around the sides, and better than an alternative that's 20% effective however well it fits. (All made-up round numbers.)