(For a bit of background info: It might seem counterintuitive, but on Windows, a “native” application “should” actually call the programming language agnostic Kernel32.dll functions directly. At least that’s the documented, stable way of doing things. Instead, Rust’s std currently goes through libc, which is also fine, but on Windows is an abstraction built on top of the Windows APIs, and is historically a lot less stable. This can cause code bloat and distribution hassles.
This is a bit different from Linux, where the abstractions are layered the other way round: the OS (POSIX) spec mostly assumes an existing libc. As a result, on Linux, going libc-less is a bit harder in my limited experience — though certainly possible if you know what you’re doing.)