A lot of bits of security rely on some level of non-determinism. Things like TCP initial sequence number generation, where every TCP connection sequence starts with a random number. There have been numerous attacks where the RNG wasn't good enough, so an attacker could determine the TCP sequencing and perform various malicious activities. Additionally, things like in-kernel VPNs, like IPSEC and WireGuard, also need RNGs for their own internal functions. Calling out to userspace for that would be painful and could potentially break in a lot of unexpected ways.

Address Space Layout Randomisation (ASLR) for one. ASLR moves around key parts of an executable to make exploitation of certain types of vulnerabilities more difficult or impossible.