Part of the usefulness of top level annotations in Haskell is that if your program has a type error, inference can fail in multiple ways. I.e. the unification algorithm might assign type T to your function F and chug along happily until it runs into a conflict in some unrelated part of the program, then throw an unhelpful error message in the case where T wasn't the type that you intended for F. By annotating F with the type you really want, you get an error message that does a better job pinpointing the problem.
This is less of an issue in ML, since ML's type system is less general than Haskell's, so the inference algorithm can't go as crazy, and you usually get good error messages even without annotations.