Intuitively I agree, from a different angle although I don't know about chemistry either, but from a supply chain perspective, for generations it's all been about optimising delivery to a consumer. Supply lines point directly at households and beyond that point it's a bit of a dark web. Random piles of crap end up... somewhere?
If the consumer became a supplier of raw recyclable materials, and those materials had value, they deserve to be compensated, and will probably be more engaged in the sorting and quality control processes. I drink a lot of beer - that makes me a great supplier of ready-made glass bottles to anyone that wants them. Rather than bulk collecting a random pile of potentially recyclable material, here's a bunch of sorted glass bottles each quarter. Anyone that can hook into that kind of idea and find some kind of economy of scale might make a killing.