Simple example:
Let's say the same pair of shoes is available in two different shops, but in one shop it's more expensive. It seem more rational to buy it in the cheaper shop. However, what if you've heard that the cheaper shop is very unethical in how it conducts the business. Is it still more rational to buy the shoes there?
And then you might also start considering this situation "in the grand scheme of things" - in the grand scheme of things does it make any difference if I buy it in shop A or B?
And at which point does it become irrational to be overthinking simple things in order to try to be rational? What if trying to always be rational is stressing you out, and turns out to be worse in the long run?