Bulgaria still holds the record of seized crypto, at 200K BTC which is at about 6.5 Billion $ ATM.
AFAIK, when the police comes to you the computer people come alongside with the guys with the guns and immediately start messing with your equipment before packing them for evidence.
How would they take your coins? If it's on an Exchange they will simply tell the exchange to hand over the dirty money. If the exchange is out of their jurisdiction, it can be harder but the cyber crime tends to be international in nature so they will probably activate some cooperation agreement and compel the exchange to hand over. If the exchange is extralegal, their best bet would be to compel you to hand it over.
The first thing the computer people do would be to take a look at the running devices and extract as much information is possible. They will take alive snapshot and manually look around your folders and browser history for points of interest. Since the raid is most likely to be as a result of an investigation they would likely have an idea what to look for. If they know that you run your business with BTC they would be looking for wallets and Exchange login info.
Once the accessible data is collected and disk images are taken and you are in custody they will start pushing you to give them access to the stuff that is locked down. Because you were investigated before the raid, they will have an estimate of your possessions and will know what to press for. If they nail you for some criminal activity, your best bet could be to cooperate and hand over your crypto if you don't want to be in prison for longer.