So what part of Chimera is "built with LLVM"? Certainly not the Linux kernel itself, that relies too heavily on GCC quirks.
Also, Nick Desaulniers and team from Google work on fixes to the toolchains and kernel to keep it that way. [1]
True, but there was a large effort to clone in LLVM nearly all the GCC extensions and quirks that the Linux kernel requires, so that nowadays the Linux kernel can be mostly compiled also with LLVM. See https://bugs.llvm.org/show_bug.cgi?id=4068 and its long list of dependencies to get an idea of what had to be done.
"Linux version 5.13.0+ (x@x) (Debian clang version 13.0.0-++20210418105309+a0898f0cecc7-1~exp1, LLD 13.0.0) #6 SMP Thu Jul 1 10:22:40 CDT 2021"