An energy-sector engineering shop had SPARCstation 2's and 4's used for running nuclear reactor Fortran compilations and simulations. The software ran on any UNIX (SCO, HP-UX, BSD, SunOS/Solaris, SGI, AIX) and I helped port it to Windows about 1997. Oddly enough, Windows of that era had extremely inefficient virtual memory swap strategies.
The university I worked at had a large Solaris deployment for internal IT systems for the CS department. They kept it for many years because it worked, it was a known quantity, and was reliable. They could've changed it over to commodity boxes running Linux or FreeBSD sooner, but that would've been a major headache for downtime, costs, and staff processes.
A friend-of-a-friend ran an extremely large deployment of Solaris boxes for batch jobs of a military data processing facility.
The scariest SunOS feature was metadisks: striped drive volumes to expand storage.