- Arch will release a new version of Xorg before the graphics card vendors release new drivers that are compatible with it. Same for kernel versions too.
- I've had gedit start crashing in new minor versions of gnome due to a setting being incompatible, needing to track that down and unset
- If you have python virtualenvs for development and system python is upgraded to a new major version, all your virtualenvs break
- If arch upgrades the major version of glibc during some random package install (rather than a system upgrade), and you don't upgrade the whole system at once, every app that didn't get upgraded will fail to start due to soname mismatches... and that can mean that pacman, sudo, etc are all busted (this has actually happened to me)
- If you do a full system upgrade and have AUR stuff installed, you need to be sure to upgrade the AUR stuff otherwise it could break due to being incompatible with any library that was upgraded.
- In general (not specific to arch linux), new versions of software break stuff all the time. You tend to hit way more of this on arch if you keep your system up to date.