The blog author seems rightfully fed up with years' worth of people obliviously asking them about children when they've chosen to live childfree. It's no surprise that this mistargeted email is received so poorly.
That said, I think it's really imprecise to infer whether someone has a child from their age, sex, and marital status. Regardless of how many 30-year-old married women in SE Railways' database show strong signs of having children (e.g., they regularly book child's fares), the consequence of incorrectly believing a woman has a child when they really don't is potentially really bad. How many infertile couples, recovering stillbirth mothers, or childfree advocates who complain eloquently enough to get to the front page of HN do you want to risk upsetting with this tone-deaf campaign email?