There's nothing that guarantees that's constant-time. It's just written in a way that's likely to be constant-time, and observed to be constant-time with current compilers, but there's no reason why a specification-compliant compiler couldn't make it variable-time tomorrow.

You can do exactly the same in Rust. Rust isn't any help there, but it doesn't obstruct you either.

We've had code in OpenSSL written in C that was constant time until a newer version of both gcc and clang recognized (mask & a | ~mask & b) as a conditional assign and could do things like turn it into a branch.

Edit: It can turn "b = foo(); c = (mask & a | ~mask & b)" into "if (mask) c = a; else c = foo();"

And indeed the XOR method is also how it's implemented in Rust.

https://docs.rs/subtle/2.4.0/src/subtle/lib.rs.html#226-244 - the impl for [u8], where the per-element ct_eq is

https://docs.rs/subtle/2.4.0/src/subtle/lib.rs.html#259-272 - the impl for u8

Which is prime example as to how C does not consider timing to be observable behavior. What the code does is that it tries to specify the operation in sufficiently complex way that makes compiler give up on any optimizations.