A DC distribution system in the home would require both a high power rectifier at the main panel to something like 125 VDC, then many smaller DC/DC converters throughout the home for your usable voltages like 5/9/15/20 V that are too low to be effectively distributed.
All of those things would need to be maintained and upgraded over the years, because there is no such thing as power electronics that last forever. After a few electrician visits, you might find that you haven't saved any money at all.
Even if you have solar, you still need a DC converter because it will not output a constant voltage let alone all of the DC voltages you need for your devices. And generation any further away than your own rooftop is going to need to be stepped up to higher-than-home voltages and then back down for use in your home - all of which is exactly why we currently use AC for distribution.