The Baghdad Battery dated around 200 BC which are speculated to have been used for electroplatting gold and silver jewellery.
More information about these devices: http://www.ancient-wisdom.com/baghdadbatteries.htm
More information about these devices: http://www.ancient-wisdom.com/baghdadbatteries.htm
Electroplating requires a much higher voltage than whatever these batteries would have put out. Apologies for the meme-y video, but Electroboom explains the issues quite well regardless: