Can anyone explain why the contact DC voltage rating of relays is often much lower (5x is no exception) than the AC rating?
Of course a higher frequency would heat the contacts even less, and I imagine you could get a relay rated for even higher voltages given a higher AC frequency.
I suspect the arc could cause the contact to stick for a while, which may increase the arc time.
AC is easier to extinguish (0A current 100 times / s), and I believe the reversible direction makes for better electroplating characteristics.