GChat is pretty idiot-proof, and platform-independent.
Also, I think video chat works better and will pretty much always work better on computer than on smartphones. There's a much better screen, you don't have to hold it just right, and it's easier to sit down and make time for a video chat on a computer. If you're looking at the numerous failed attempts at video chat on phones, I can see how you'd see it as useless, but Skype is different.