I would definitely read the "How I turned down a $300,000 job at bigcorp to found a startup that crashed and burned 18 months later" story.
I learned a ton and didn't regret it for an instant. Moved on to a new startup 2 years ago when it became clear the first was a dead end. Google recruiters continued to ping me religiously every 6 months regardless.
Moral of the story: Google, MSFT, Facebook, etc will all still be there in 2 years. Especially if you're early in your career and don't need the cash today, go wherever you will learn the most.