In some sense, yes. If you read this post of his though: http://calnewport.com/blog/2008/11/25/case-study-how-i-got-t... you get the sense that it's not only about brute forcing hours, but also spending those hours wisely. In the case of math, that was making sure he could understand and recreate every proof perfectly. This was probably a lot more effective than spending those hours, say, studying only problem sets or lecture notes.