I don't think overscan would be an issue. The TMS9918 is also (the equivalent of) 320 pixels wide, and it was used in many different home computers and game consoles intended to connect to the family TV. There's no overscan issue, unless it's connected to an Apple II monitor.
When the TMS9918 is connected to an Apple II monitor there is a huge overscan issue, since the monitor is tuned for the narrower Apple II screen. It looks like this: https://imgur.com/rGcRpw0
That's what got me thinking about this issue is the first place.