A hundred dollar bill has not represented an IOU since giving up the gold standard.
And honestly, that's really not so different than gold. Why would the gold standard work? What intrinsic value does gold have? Again it only has that value because we trust it. If we stopped caring about gold, maybe if asteroid mining were to quickly result in 10 times the amount of gold that's currently available, gold would quickly lose that trust; same as when a government started printing money with wild abandon. As long as governments are responsible about the money supply, money is just as good as gold. But only as long as they are.
As a example of how much the value of fiat currency depends on taxation: https://www.irs.gov/taxtopics/tc420
Even if you barter without using any currency, the IRS wants a cut.