The butterfly effect only works when a physical system is on the knife's edge, that it is prone to unstable/chaotic behavior. While it is conceivable that these conditions could exist at times (all the way from quantum level to saying "I'd like strawberry" vs "I'd like vanilla"), it seems unlikely to me that those conditions happen frequently enough that one's free will can direct the desired outcome consistently.
Secondly, the idea ignores the problem of how this free will "knows" which quantum events to perturb such that their effects would cause the pachinko machine of sub-atomic -> atomic -> molecular -> nervous system interactions to achieve its intended outcome.