I don't know how SQLite scales for large data sets, but for a small tasks it's fantastic, and can be trivially ported to something like Postgres.
> implementation details of the KV/heap layer with some meaningful transactional properties seem more interesting
There is undoubtedly a real beauty in LMDB's data structures, and it is impressive to see how Rockset have re-engineered RocksDB to become cloud-native …but my own feeling is that the SQL/whatever, distributed consistency and federation layers of a DBMS encompass some seriously hard and fascinating problems. What if the web could behave like a cohesive offline-first database for all of human knowledge after all?
Now I think about it, "interesting" has a pretty loose definition too!