I've been using it at my daily driver since 2010. At first, I stuck with it because it wasn't Google. I noticed right away that it would turn up different results from what I came to expect at Google. Then I noticed that, although they were different, they were just as effective and getting me the information I needed. For example, it would prominently place websites I may not have heard of and that didn't show up high in the Google results, but when I just went with it anyway I discovered that relevant information that solved my problem was there.
I think a lot of people try out DDG, see some sites they don't recognize and then dismiss it as producing bad results because they are not Google results. We basically trained ourselves to use Google as the benchmark for what a search engine should produce - not in general terms of reliability of information but exact results. Then something else doesn't produce those same results and it's crap. Or, for a particular query, the top Google result is the best and the second or third DDG result is the best and that makes it crap. Search has always been a little bit of an art where you have to learn how to do it effectively and how to quickly parse your results.
I use Google maybe a handful of times a year and I would rarely find better results over there. It got to the point where I really didn't like their result page at all compared to DDG. It seemed spammy and it was difficult to parse. For a long time, they were fiddling around with things like displaying the full URL or making ads look more like legitimate results. On the other hand, DDG was doing things like zero click info and instant answers. I came to prefer their results much better. I showed up for the privacy and after a little while I stayed because it worked better.
I have tried Google a few times recently and they are doing some cool stuff with their results page. I particularly like the "featured snippets" and "people also ask" sections. Featured snippets is similar to DDG's zero click stuff, but it works with more complex queries like "best travel trailers for first time owners". But for years, DDG was doing cool things with the results page while Google was just a list of pages with ads, videos or news featured prominently at the top.