With comments like the GP you'd think FB hobbled along with PHP on its way to becoming as big as it is now.
http://techcrunch.com/2008/05/01/twitter-said-to-be-abandoni...
My point is that choice of language is not what will likely stand in your way of becoming a monumental startup success. Yet people will insist on promoting language wars as if it will.
(I think Twitter ended up using Scala, didn't they?)
I don't know what's the "official" (or real) story on current Twitter architecture.
I agree that some people take the choice of language and architecture a little to seriously. Of course you can start a blockbuster business on PHP and MySQL - people prove that frequently!
http://www.quora.com/What-are-the-crawling-horrors-of-PHP
Why facebook has stayed on PHP:
http://www.quora.com/Why-hasn-t-Facebook-migrated-away-from-...