They did have a null hypothesis and a control group. The problem was that the non-control was different from the control in a way they were careless with, that the scientific methodology does not catch (that peer review and replication ought to have caught). e.g. if the favorable results were better explained by subjects seeing soup taken out of the pot vs. from the can rather than the temperature itself.
It is absolutely possible to find people with an abnormal number of fingers or toes.
https://en.wikipedia.org/wiki/Oligodactyly
https://en.wikipedia.org/wiki/Polydactyly
If 100% of the studied humans have 10 fingers and 10 toes, something's wrong with the study. In this case, the problem is the extremely small sample size: it simply doesn't represent the general human population. In the article author's case, a programming error caused these results.
0% and 100% are always suspect no matter the context they appear in.