Most of those materials are reverse engineer-able, though. This has a significant impact on the big manufacturer's bottom lines... they derive most of their profit from materials, just like regular printers.
I'll just leave this here: http://open3dp.me.washington.edu/
Specifically: http://open3dp.me.washington.edu/2009/10/plaster-based-powde...
See how cheap that is? Crazy...