Isn't that strange? Wouldn't you think that undecidable propositions would be scattered through mathematics and turn up at curious and interesting moments in different fields? But apparently that's not generally the case. The Goldbach conjecture (Knuth) and of course the Riemann Hypothesis have been mentioned as possible candidates (but you might have said the same thing about Fermat's last theorem 30 years ago). If we did find a first-rank conjecture in number theory or some other area that's undecidable in ZFC (or whatever system) then we would at last be stepping through the door that Gödel opened for us.