They know too much, they often don't recognize how many pieces of assumed information they're injecting into their so-called explanations. You often get circular explanations in addition to circular reasoning and it can be off-putting.
A better use of time is to get someone who is just started to exhibit competence to write the docs. They won't assume the jargon, they can't assume deep knowledge, and because they're living right at the pain point they can be especially sympathetic. And if what they explain is dead wrong, this is your chance to correct a horrible misunderstanding before they get too far along. Pointing out the 'false friends' in a system early on can be pretty powerful. Educationally or as an opportunity for improving the system.
In other words, I'd encourage you to invite new people to contribute. Just keep an eye on what they do and be ready to jump in with corrections.