I wish more devices would run on PoE. It's DC, it's easy to install, it carries power and data. There are some (but few) PoE light fixtures, but not as many as I'd like.
Given the degree of fire risk in houses that's associated with 230V/10A wiring and devices, I do wonder how much safer it would be to have fewer AC/DC transformers scattered around the house with DC wiring.
If it's just a matter of providing alternative circuitry for low-power devices, presumably you can already improve safety by just using lower-current circuit breakers.
A good point - I guess I'm mostly thinking about the volume of things in the house that don't really need access to even a fraction of the 2.4kW available; having moved from incandescent bulbs to LEDs, I've got a bunch of unnecessary power supply and per-bulb transformers, for example.