Is guix's documentation any better? I mean - teach me the theory, but also show me practical examples making use of it so I could remember?
I've never found the documentation to be outdated or grossly misleading.
That's because Guix is an operating system :D
There is little difference between Guix and the Guix system when looking a little more closely. Even when using Guix as a package manager it won't link with any of your OS libraries, so you end up downloading or building variants of libraries that you may already have on your host operating system --- that's by design as it unlocks reproducible builds.
The scheme you have now is confusing for no reason. I saw this news on Phoronix and even after reading the article I couldn't tell if it was the pkg manager or the distro that had reached 1.0 (I guess it's both?).
I understand what you mean by the difference. (I currently overlay Nix on top of a different Linux distribution.) But without the "system" part, Guix on its own is still not strictly an OS, since there's no kernel being deployed. A pedantic point, but an accurate one I think. :)
Personally the thing that holds me back from Guix is their (understandable) insistence on packaging libre/free software only. Guix looks like it has better usability than Nix, IMO, but I don't want to jump through extra hoops to get non-free software installed.