We also had the police employing radar detector-detecting devices 15 years ago that could detect every single radar detector on the market in 2004, and none of those radar detectors were intentionally transmitting a signal: https://en.wikipedia.org/wiki/Radar_detector_detector
An image classifier with a human check doling out fixed penalties would be more effective than this. So would a warning system on phones that shamed drivers. Neither are within the resources of the police to develop (as nearly all police in the UK are local).
Probably not - Computer Misuse Act, s.10:
> Sections 1 to 3A have effect without prejudice to the operation—
> (a)in England and Wales of any enactment relating to powers of inspection, search or seizure or of any other enactment by virtue of which the conduct in question is authorised or required