It's actually 63 million people, roughly 20%.
https://www.usatoday.com/story/news/2017/08/14/63-million-am...
https://www.usatoday.com/story/news/2017/08/14/63-million-am...
I'd say that "exposed to potentially unsafe water more than once during the past decade" is pretty far from "20% of Americans don't have clean tap water". If anything, I'd rather say it's impressive that 80% of Americans haven't been exposed to potentially unsafe water more than once in a decade!