I play a game called Elite Dangerous with my Oculus rift, and the UX of being able to have holographic windows around my person that I can look at to activate and control is so insanely powerful and so freeing, and I'm literally willing to drop multiple thousands of dollars on something right now that can give that experience with normal desktop software right now.
Sadly the Rift lacks any way to see the real world when it's on (which makes using a keyboard and mouse more difficult), and the resolution still has a ways to go before I can comfortably use it like this, not to mention the software still needs work for this use case.
But I can't wait until the day when I can get rid of the monitors on my desk and replace them with a headset. Being able to place normal 2d windows around my person, be able to maybe use some limited gestures to control them, and then the same keyboard and potentially mouse that in used to.