I seriously enjoy humor or political / debate podcasts, especially while commuting, but technical podcasts never stick.

I find when getting into a new framework (something like Rails or React) then it's an interesting bit of "immersion learning" to throw on the latest episode of the big associated podcast. Maybe I pick up a bit of knowledge, but just hearing people speak naturally about the framework helps me build a fuzzy roadmap in my head of the big subjects to tackle.