Well, no. If 5A flows through you from hand-to-hand, sustained for longer than an instant, you're probably dead. But I've touched live power supply terminals for something rated for 20A without a second thought.
And if there's a 10kV differential between your left and your right hand, sustained for longer than an instant... You're probably dead. But I've touched a 10kV power supply (not on purpose, this one), and...still here.
So! What gives?
Well. Place a 0.1 ohm resistor across that power supply. 18V across 0.1 ohms will produce a current of 180A. This will dissipate more than 3kW in the resistor, and it will very rapidly disassemble itself. But that doesn't happen!
Okay, now put a 10 megaohm resistor across that power supply. It's 5A, right? So 5A across 1 megaohm will produce a voltage of 5000kV. This will dissipate 25 megawatts, and destroy the resistor even faster. This also doesn't happen!
In fact, what will happen in the first case is that 5A, not 180A flows (assuming the PSU doesn't detect the apparent short and shut down entirely.). But Ohm's law says that if 18V is placed across a 0.1 ohm resistor, 180A must flow!
Ah, but 18V isn't placed across the resistor. Instead, as current draw approaches the 5A limit, the power supply starts dropping the voltage. No more than 5A will flow, even if that means the voltage must be decreased.
And 5A won't flow through the 1 megaohm resistor, either. Instead, no more than 18V will be placed across the load, even if that means the current must decrease.
So, the power supply won't kill you UNLESS your skin resistance is low enough that 18V causes a lethal (very roughly roughly 1A) current to flow through you. Luckily, humans have a fairly high skin resistance, at least when we're dry, and 18V is fine.
It's not the volts that kill you, it's the amps which the volts are directly related to. 10kV across your body, sustained for a bit, will kill you dead, modulo some sort of miracle. 10kV at 1mA across your body ... is impossible. If you touch a 10kV, 1mA supply- the voltage will drop so that only 1mA flows.
It's not the voltage limit on the power supply that kills you. It's not the current limit on the power supply that kills you. Both need to be high enough to do you in.